06 August 2014

Waiting out Bertha - Update #4

Everything went pretty smoothly while we were waiting for Bertha to pass.  We got in one more science day before heading for port to wait out the storm.

If you want to see our cruise track and current location, you can check out this website that tracks most ships, including ours.

Below are our normal daily updates.  Since not too much happened, I've included a section at the end to start explaining the science that is happening on board in more detail.  This time, I'll be talking about trace metal chemistry.

Day 5
For the most part, this day looked a lot like day 4.  We had the aerosol sampler out overnight, and were headed south, into the wind.  Around 2am, we turned it off and returned to the center of the eddy we've been in for the past few days.  After another sunrise CTD cast, we deployed the towfish and began towing it in a circle around our drifters.

At one point, it began raining really hard while the towfish was out.  So there was a mad scramble to get the rain collector out to catch more rain.  It ended up being only a brief shower, but we got a bit of rain out of it.  Then, we finished up with the towfish and proceeded to do the daily noon PAR cast.  After that, we completed another shallow CTD cast to get the conditions after the brief rain event.

Rather wet scientists after dashing out in the rain to turn on the rain collector
Up until this point, we hadn't been getting quite as many surface samples as we wanted from the towfish.  So when we did the shallow CTD cast, we decided to sample from the ship's underway system at the same time.  The underway system is always on and samples at the bottom of the ship.  However, there is a good chance that the samples wouldn't be representative of the surface water, since there are probably extra organisms growing in or near the sampling system.  We compared the samples to the CTD surface cast, and it turned out the values did not match, so we probably won't use the underway system for sampling nutrients or chlorophyll.

Our final task of the day was to retrieve two of the three drifters.  We decided to leave one out to continue collecting data, but didn't want to risk more than one with Bertha approaching.  We will return for the last one after Bertha has passed.

Pulling the drifter and attached drogue out of the water

Day 6
Not much went on today.  We used this time to catch up on lab work and relax.  We arrived back in port at around 2pm, and spent time calling friends and family and catching up with the internet while the crew fueled up the ship and did some maintenance work.

Passing the lighthouse on our way back into port

Trace metal oceanography
In the cruise updates, I've mentioned deploying our trace metal CTD, at least until the winch for it broke.  Now, I'd like to give you a general idea of what I mean when I say "trace metal".

I've already talked a bit about nutrients and phytoplankton.  Measuring nutrients is one of the main activities for this cruise.  Major nutrients in the ocean are essentially various forms of nitrogen, phosphorus, and carbon.  If enough nutrients of each type are available, phytoplankton will grow and reproduce.  If one type is missing or used up, growth will slow and stop.  We call the missing type the "limiting nutrient".  In oceanographic history, scientists discovered a quandry.  They found large amounts of all nutrients, but for some reason, the phyotplankton weren't growing and using them up.  The regions where this phenomenon occurred became known as High Nutrient Low Chlorophyll (HNLC) regions.  Something besides the nutrients was acting as the limiting factor.

It was eventually discovered that along with the major nutrients, phytoplankton also need incredibly small amounts of other nutrients, called micronutrients.  One of these was iron.  There is not a lot of iron floating around in the ocean, but it normally doesn't act as a limiting factor except in certain HNLC regions.

So, once it was discovered that iron was another important, albeit small, nutrient, scientists set out to measure it as well.  This was where they ran into problems.  Iron is available is such low concentrations that any measurements were contaminated.  The ship itself contaminated the water, any metal on the CTD or the chain or the winch also contaminated the water.  Basic laboratory equipment and normal lab coats and gloves contaminated samples.  It was virtually impossible to get an accurate iron measurement with standard oceanographic equipment.

Working in the trace metal clean laboratory on board - Photo courtesy of Bettina Sohst.
This was where "trace metal clean" protocols came in.  Scientists figured out how to make their working environment clean enough that accurate iron measurements could be made.  They set up clean laboratories with special ventilating systems to keep any traces of iron out.  Plastic bottles used to collect samples are rigorously cleaned, using acid baths that leave no trace behind.  Special CTD set-ups were designed to ensure no contamination of the ocean during sampling.

Trace metal CTD about to be deployed
In our case, we have a trace metal clean CTD and the towfish is also trace metal clean.  There is a clean laboratory set up in a "van" on the ship - it is a portable lab the size of a shipping container that can be attached to the back deck.  When we do a trace metal cast, the trace metal CTD goes in on the opposite side of the ship as the normal CTD, so there is no contamination.  The trace metal CTD doesn't collect any samples in the upper 10m of the water, to avoid any contamination from the ship.  In order to sample the surface water for iron, we use the towfish.  It is put in the water while the ship is moving, and is held out to one side, so that it collects water untouched by the ship.  Every time we use it, it gets flushed with seawater before any samples are collected.  When not in use, all nozzles and openings are covered with disposable plastic to keep contamination to a minimum.

Preparing to deploy the towfish
As you can imagine, measuring for iron requires just as many precautions.  None of the measurements are being performed on board for that reason.  We are collecting the samples and properly storing them to be tested in a stationary lab once we get back.

Now, when I mention our trace metal CTD, you will know that I really mean a "trace metal clean" CTD where samples can be taken to measure the micronutrient iron.

Coming up, we're back out at sea, taking more measurements and we’ll be deciding soon where to go next.

More posts in this series:
Upcoming Cruise
Cruise Delays
Upcoming Cruise, Part II
Update #1
Update #2
Update #3
Update #5
Update #6 
Update #7 
Update #8 
Update #9